Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control.

Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control. Research Abstract Details 

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Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control. Abstract Text:

Sumitra Mukhopadhyay,William H Armstrong,

A sterically hindered carboxylate ligand is used to synthesize the first transition metal complex containing both bis-mu-oxo and bis-mu-carboxylato groups, [Mn2(mu-O)2(mu-ArtolCO2)2(bpy)2]+. However, methyl substitution on the chelating bipyridine ligand results in the formation of a strikingly different and novel hexanuclear species, [Mn6(mu-O)4(mu3-O)4(mu-ArtolCO2)2(dmb)6]4+. Steric interactions between the bridging carboxylates and chelating pyridine-based ligands determine the nuclearity of the complexes formed.

Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control. Publishing Authors By Initials

S Mukhopadhyay,WH Armstrong,

For similar organic chemicals: organometallic compounds research abstracts see: organic chemicals: organometallic compounds research

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Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 125

Page Numbers: 13010-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 29

MONTH: Oct

YEAR: 2003

Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control. Keywords Mesh Terms:

KEYWORDS: Organometallic Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control. Information

Substance Name: Manganese

Registry Number: 7439-96-5

Grant and Affiliation Information for Multinuclear oxo-bridged manganese complexes with a bulky substituted benzoate ligand: novel species obtained by using steric control.

AFFILIATION: Department of Chemistry, Eugene F. Merkert Chemistry Center, Boston College, 2609 Beacon Street, Chestnut Hill, MA 02467-3860, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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