Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes.

Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Research Abstract Details 

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Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Abstract Text:

Eric C Brown,Brandon Johnson,Sara Palavicini,Benjamin E Kucera,Luigi Casella,William B Tolman,

A general method for the preparation of multidentate ligands comprised of a multi-imine platform derived from 1,1,1-tris(aminomethyl)ethane or tris(aminoethyl)amine connected to bi- and tridentate N-donor chelates has been developed. The feasibility of the method has been demonstrated through the synthesis and characterization of a large set of these ligand types. Complexation to Cu(I) was accomplished for several cases, yielding tri- and tetracopper(I) complexes that have been characterized in solution by NMR spectroscopy and conductivity, and in the solid state by elemental analysis, mass spectrometry, and/or X-ray crystallography. These complexes are potentially useful for modeling multicopper protein active sites.

Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Publishing Authors By Initials

EC Brown,B Johnson,S Palavicini,BE Kucera,L Casella,WB Tolman,

For similar inorganic chemicals: elements: nitrogen research abstracts see: inorganic chemicals: elements: nitrogen research

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Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Dalton transactions (Cambridge, England : 2003)

VOLUME:

Page Numbers: 3035-42

Journal Abbreviation:

ISSN: 1477-9226

DAY: 8

MONTH: 06

YEAR: 2007

Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 101176026

Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Keywords Mesh Terms:

KEYWORDS: Nitrogen

MESH TERMS: chemistry

Chemical & Substance for Abstract: Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Information

Substance Name: Nitrogen

Registry Number: 7727-37-9

Grant and Affiliation Information for Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes.

AFFILIATION: Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant St. SE, Minneapolis, MN 55455, USA.

Country: England

AGENCY: United States NIGMS

GRANT: GM68307

ACRONYM: GM

MEDLINETA: Dalton Trans

REFSOURCE: Dalton Trans. 2007 Jul 28;(28):3093

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