Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study.

Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study. Abstract Text:

Manickam Matheswaran,Subramanian Balaji,Sang Joon Chung,Il Shik Moon,Manickam Matheswaran,Subramanian Balaji,Sang Joon Chung,Il Shik Moon,

The mediated electrochemical oxidation (MEO) process using cerium(IV) in methanesulphonic acid (MSA) as the oxidizing medium was employed for the mineralization of phenol in batch and continuous feeding modes. Although nitric acid was an extensively studied electrolyte for organic mineralization reactions in MEO processes it does possess the problem of NO(x) gas production during the reduction of nitric acid in the cathode compartment of the electrochemical cell. This problem could be circumvented by proper choice of the electrolyte medium such as MSA. The mediator cerium in MSA solution was first oxidized to higher oxidation state using an electrochemical cell. The produced Ce(IV) oxidant was then used for the destruction of phenol. It was found that phenol could be mineralized to CO2 by Ce(IV) in MSA. The evolved CO2 was continuously measured and used for the calculation of destruction efficiency. The destruction efficiency was observed to be 85% based on CO2 evolution for 1000 ppm phenol solution at 80 degrees C in continuous feed mode.

Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study. Publishing Authors By Initials

M Matheswaran,S Balaji,SJ Chung,IS Moon,M Matheswaran,S Balaji,SJ Chung,IS Moon,

For similar abstracts research abstracts see: abstracts research

PUBMED ID PMID:

MEDLINE DATE:

Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Chemosphere

VOLUME: 69

Page Numbers: 325-31

Journal Abbreviation: Chemosphere

ISSN: 0045-6535

DAY: 2

MONTH: 07

YEAR: 2007

Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 320657

Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study. Keywords Mesh Terms:

KEYWORDS:

MESH TERMS:

Chemical & Substance for Abstract: Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study. Information

Substance Name:

Registry Number:

Grant and Affiliation Information for Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study.

AFFILIATION: Department of Chemical Engineering, Sunchon National University, # 315 Maegok Dong, Suncheon 540-742, Chonnam, Republic of Korea.

Country: England

AGENCY:

GRANT:

ACRONYM:

MEDLINETA: Chemosphere

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Mineralization of phenol by CeIV-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study Related Publications

• (Ta/Si) multilayer as a wide-bandpass monochromator material.
• A peroxisome proliferator-activated receptor gamma antagonist induces vimentin cleavage and inhibits invasion in high-grade hepatocellular carcinoma.
• Antisense targeting of TGF-beta1 augments BMP-induced upregulation of osteopontin, type I collagen and Cbfa1 in human Saos-2 cells.
• Aqueous extract of Magnolia officinalis mediates proliferative capacity, p21WAF1 expression and TNF-alpha-induced NF-kappaB activity in human urinary bladder cancer 5637 cells; involvement of p38 MAP kinase.
• Common genetic variation within the low-density lipoprotein receptor-related protein 6 and late-onset Alzheimer's disease.
• Determination of eperisone in human plasma by liquid chromatography-ESI-tandem mass spectrometry.
• Estimation of potential health gains from reducing multiple risk factors of stroke in Korea.
• How home care and hospice nurses can assist adolescents when a parent is seriously ill: adolescents with seriously ill family members.
• Hysteroscopic resection of the vaginal septum in uterus didelphys with obstructed hemivagina: a case report.
• Keeping up to date.
• Microcalcification detection in 3-d breast ultrasound.
• Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study.
• Neuroprotective activity of triterpenoid saponins from Platycodi radix against glutamate-induced toxicity in primary cultured rat cortical cells.
• On-line analysis of a continuous-flow ozonolysis reaction using Raman spectroscopy.
• Performance measurement of the microPET focus 120 scanner.
• Pomiferin, histone deacetylase inhibitor isolated from the fruits of Maclura pomifera.
• Relations between age, weight, refractive error and eye shape by computerized tomography in children.
• Simple and highly efficient synthesis of 3'-deoxy-3'-[18F]fluorothymidine using nucleophilic fluorination catalyzed by protic solvent.
• Stereoselective [2,3]-sigmatropic rearrangements of unstabilized nitrogen ylides.
• System for inducible expression of cre-recombinase from the Foxa2 locus in endoderm, notochord, and floor plate.
• The role of PET/CT for evaluating breast cancer.
• Type I collagen-induced pro-MMP-2 activation is differentially regulated by H-Ras and N-Ras in human breast epithelial cells.
• WNTS and WNT receptors as therapeutic tools and targets in human disease processes.
• [A nationwide survey on current conditions of school health education]
• [Anger, cardiovascular health and depression in middle-aged Korean men: the mediating effect of social support]
• [Expression of caveolin in hepatocellular carcinoma: association with unpaired artery formation and radiologic findings]
• [Health perception, body image, sexual function and depression in menopausal women according to menopausal stages]
• [Renal dysfunction after spontaneous bacterial peritonitis in cirrhosis: incidence and risk factors]
• [Surgical treatment of sclerosing hepatocellular carcinoma]
• [Usefulness of serum alpha-fetoprotein (AFP) as a marker for hepatocellular carcinoma (HCC) in hepatitis C virus related cirrhosis: analysis of the factors influencing AFP elevation without hcc development]