Metal vinylidenes as catalytic species in organic reactions.

Metal vinylidenes as catalytic species in organic reactions. Research Abstract Details 

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Metal vinylidenes as catalytic species in organic reactions. Abstract Text:

Barry M Trost,Andrew McClory,

Organic vinylidene species have found limited use in organic synthesis owing to their inaccessibility. In contrast, metal vinylidenes are much more stable and may be readily accessed through transition-metal activation of terminal alkynes. These electrophilic species may be trapped by a number of nucleophiles. Additionally, metal vinylidenes can participate in pericyclic reactions and processes that involve migration of a metal ligand to the vinylidene species. This Focus Review addresses the reactions and applications of metal vinylidenes in organic synthesis.

Metal vinylidenes as catalytic species in organic reactions. Publishing Authors By Initials

BM Trost,A McClory,

For similar inorganic chemicals: metals research abstracts see: inorganic chemicals: metals research

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Metal vinylidenes as catalytic species in organic reactions. Journal Published:

PUBLICATION TYPE: Review

Journal: Chemistry, an Asian journal

VOLUME: 3

Page Numbers: 164-94

Journal Abbreviation:

ISSN: 1861-471X

DAY: 1

MONTH: Feb

YEAR: 2008

Metal vinylidenes as catalytic species in organic reactions. Information

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LANGUAGE: eng

NlmUniqueID: 101294643

Metal vinylidenes as catalytic species in organic reactions. Keywords Mesh Terms:

KEYWORDS: Metals

MESH TERMS: chemistry

Chemical & Substance for Abstract: Metal vinylidenes as catalytic species in organic reactions. Information

Substance Name: Carbon

Registry Number: 7440-44-0

Grant and Affiliation Information for Metal vinylidenes as catalytic species in organic reactions.

AFFILIATION: Department of Chemistry, Stanford University, Stanford, CA 94305, USA. bmtrost@stanford.edu

Country: Germany

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MEDLINETA: Chem Asian J

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