Mechanically regulated rotation of a guest in a nanoscale host.

Mechanically regulated rotation of a guest in a nanoscale host. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Mechanically regulated rotation of a guest in a nanoscale host. Abstract Text:

Alessandro Scarso,Hideki Onagi,Julius Rebek,

The spinning rate of an encapsulated cyclophane guest is affected by the "size" of the coguests.

Mechanically regulated rotation of a guest in a nanoscale host. Publishing Authors By Initials

A Scarso,H Onagi,J Rebek,

For similar polycyclic compounds research abstracts see: polycyclic compounds research

PUBMED ID PMID:

MEDLINE DATE:

Mechanically regulated rotation of a guest in a nanoscale host. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 12728-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 13

MONTH: Oct

YEAR: 2004

Mechanically regulated rotation of a guest in a nanoscale host. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Mechanically regulated rotation of a guest in a nanoscale host. Keywords Mesh Terms:

KEYWORDS: Polycyclic Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Mechanically regulated rotation of a guest in a nanoscale host. Information

Substance Name: Carbon Tetrachloride

Registry Number: 56-23-5

Grant and Affiliation Information for Mechanically regulated rotation of a guest in a nanoscale host.

AFFILIATION: The Skaggs Institute for Chemical Biology and The Department of Chemistry, The Scripps Research Institute, MB-26, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: GM 50174

ACRONYM: GM

MEDLINETA: J Am Chem Soc

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Mechanically regulated rotation of a guest in a nanoscale host Related Publications

• A cavitand stabilizes the Meisenheimer complex of SNAr reactions.
• A deep cavitand catalyzes the Diels-Alder reaction of bound maleimides.
• A deep, water-soluble cavitand acts as a phase-transfer catalyst for hydrophobic species.
• A functionalized, deep cavitand catalyzes the aminolysis of a choline derivative.
• A reversible reaction inside a self-assembled capsule.
• A synthetic mimic of protein inner space: buried polar interactions in a deep water-soluble host.
• Adaptations of guest and host in expanded self-assembled capsules.
• An NMR study of the rates of single-molecule exchange in a cylindrical host capsule.
• Assembly and exchange of resorcinarene capsules monitored by fluorescence resonance energy transfer.
• Assembly of hybrid synthetic capsules.
• Assembly of resorcinarene capsules in wet solvents.
• Cavitands with introverted functionality stabilize tetrahedral intermediates.
• Coiled molecules in spring loaded devices.
• Contortions of encapsulated alkyl groups.
• Expanded capsules with reversibly added spacers.
• Experimental and computational probes of a self-assembled capsule.
• Extraction of hydrophobic species into a water-soluble synthetic receptor.
• Guest recognition with micelle-bound cavitands.
• Heterocyclic alpha-helix mimetics for targeting protein-protein interactions.
• Individual solvent/solute interactions through social isomerism.
• Isotopomer encapsulation in a cylindrical molecular capsule: a probe for understanding noncovalent isotope effects on a molecular level.
• Longer guests drive the reversible assembly of hyperextended capsules.
• Moving targets: recognition of alkyl groups.
• Polycaps: Reversibly formed polymeric capsules.
• Reactivity and molecular recognition: amine methylation by an introverted ester.
• Self-assembly dynamics of a cylindrical capsule monitored by fluorescence resonance energy transfer.
• Self-complexed deep cavitands: alkyl chains coil into a nearby cavity.
• Social isomers in encapsulation complexes.
• Stabilization of labile carbonyl addition intermediates by a synthetic receptor.
• Steric and magnetic asymmetry distinguished by encapsulation.