Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM.

Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM. Research Abstract Details 

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Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM. Abstract Text:

Alexandr Marchenko,Nathalie Katsonis,Denis Fichou,Corinne Aubert,Max Malacria,

We report on the formation of self-assembled monolayers of 13-(trimethylsilyl)-1-tridecene-6,12-diyne [C13H17-Si(CH3)3], an organosilane derivative with a linear polyunsaturated chain, on Au(111) substrates. Molecular resolution STM images recorded at the liquid-solid interface between gold and tetradecane reveal a long-range and densely packed hexagonal lattice with a ( radical3 x radical3)R30 degrees -like structure commensurate against gold adlattice.

Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM. Publishing Authors By Initials

A Marchenko,N Katsonis,D Fichou,C Aubert,M Malacria,

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Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 124

Page Numbers: 9998-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 28

MONTH: Aug

YEAR: 2002

Long-range self-assembly of a polyunsaturated linear organosilane at the n-tetradecane/Au(111) interface studied by STM. Information

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LANGUAGE: eng

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AFFILIATION: CEA-Saclay, Service de Physique et Chimie des Surfaces et Interfaces, DRECAM/DSM, 91191 Gif-sur-Yvette, France.

Country: United States

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MEDLINETA: J Am Chem Soc

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