Kinetic explosion and bistability in adsorption and reaction of acetic acid on Pd(110).

Kinetic explosion and bistability in adsorption and reaction of acetic acid on Pd(110). Research Abstract Details 

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Kinetic explosion and bistability in adsorption and reaction of acetic acid on Pd(110). Abstract Text:

Michael Bowker,Chris Morgan,Vladimir P Zhdanov,Michael Bowker,Chris Morgan,Vladimir P Zhdanov,

The adsorption and reaction of acetic acid with Pd(110) have been studied using thermal molecular beam reaction measurements and temperature-programmed desorption. Acetic acid adsorption results in the formation of acetate species which decompose to produce coincident CO(2) and H(2) desorption from the surface. C is deposited on the surface from the dehydrogenation of the methyl group. In combination, these steps are found to exhibit unusual kinetics including (i) a "surface explosion" during heating and (ii) bistability in the reaction profile for heating and cooling curves. This is the first report of such behaviour for a complex system during in situ reaction.

Kinetic explosion and bistability in adsorption and reaction of acetic acid on Pd(110). Publishing Authors By Initials

M Bowker,C Morgan,VP Zhdanov,M Bowker,C Morgan,VP Zhdanov,

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Kinetic explosion and bistability in adsorption and reaction of acetic acid on Pd(110). Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Physical chemistry chemical physics : PCCP

VOLUME: 9

Page Numbers: 5700-3

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ISSN: 1463-9076

DAY: 13

MONTH: 09

YEAR: 2007

Kinetic explosion and bistability in adsorption and reaction of acetic acid on Pd(110). Information

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LANGUAGE: eng

NlmUniqueID: 100888160

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Grant and Affiliation Information for Kinetic explosion and bistability in adsorption and reaction of acetic acid on Pd(110).

AFFILIATION: Wolfson Nanoscience Laboratory, School of Chemistry, Cardiff University, Cardiff, UKCF9 3TB. bowkerm@cf.ac.uk

Country: England

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MEDLINETA: Phys Chem Chem Phys

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