Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer.

Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer. Abstract Text:

Hemant K Sharma,Francisco Cervantes-Lee,Keith H Pannell,

Treatment of FpCH2SiR2Cl [Fp = (eta5-C5H5)Fe(CO)2] with lithium diisopropylamide leads to the formation of new metallacycle complexes. When R2 = Me2 and MenBu, these ring-open to form a new class of organometallic polymer. When R2 = nBu2, the metallacycle resists ring-opening and may be structurally characterized as the Ph3P-substituted species.

Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer. Publishing Authors By Initials

HK Sharma,F Cervantes-Lee,KH Pannell,

For similar inorganic chemicals: silicon compounds: silanes research abstracts see: inorganic chemicals: silicon compounds: silanes research

PUBMED ID PMID:

MEDLINE DATE:

Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 1326-7

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 11

MONTH: Feb

YEAR: 2004

Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer. Keywords Mesh Terms:

KEYWORDS: Silanes

MESH TERMS: chemistry

Chemical & Substance for Abstract: Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer. Information

Substance Name: Silanes

Registry Number: 0

Grant and Affiliation Information for Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer.

AFFILIATION: Department of Chemistry, University of Texas at El Paso, El Paso, Texas 79968-0513, USA.

Country: United States

AGENCY:

GRANT:

ACRONYM:

MEDLINETA: J Am Chem Soc

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Isolation and ring-opening of new 1-sila-3-metallacyclobutanes eta 5-C5H4FeCO2CH2SiR2 leading to a new class of organometallic polymer Related Publications

• "Crossed-field" excitation of an acoustic superlattice with matched boundaries: theory and experiment.
• Clonal turnover versus clonal decay: a null model for observed patterns of asexual longevity, diversity and distribution.
• Coalescence in a metapopulation with recurrent local extinction and recolonization.
• Consequences of inbreeding depression due to sex-linked loci for the maintenance of males and outcrossing in branchiopod crustaceans.
• Density-dependent regulation of the sex ratio in an annual plant.
• Density-dependent self-fertilization and male versus hermaphrodite siring success in an androdioecious plant.
• Ecological differentiation and diploid superiority across a moving ploidy contact zone.
• Fabrication and evaluation of a freestanding pyroelectric detector made from single-crystal LiNbO(3) film.
• Identification of differentially secreted biomarkers using LC-MS/MS in isogenic cell lines representing a progression of breast cancer.
• Intramolecular chalcogen-tin interactions in (o-MeE-C6H4)CH2SnPh3-nCln (E = S, O; n = 0, 1, 2), characterized by X-ray diffraction and 119Sn solution and solid-state NMR.
• Isolation and ring-opening of new 1-sila-3-metallacyclobutanes (eta 5-C5H4Fe)(CO)2CH2SiR2 leading to a new class of organometallic polymer.
• Preparation of nasal secretions for proteome analysis.
• Reduced responses to selection after species range expansion.
• Studies on certain biological characteristics of Malleomyces mallei and Malleomyces pseudomallei; morphology, cultivation, viability, and isolation from contaminated specimens.
• Studies on certain biological characteristics of Malleomyces mallei and Malleomyces pseudomallei; virulence and infectivity for animals.