Ion transfer at nanointerfaces between water and neat organic solvents.

Ion transfer at nanointerfaces between water and neat organic solvents. Research Abstract Details 

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Ion transfer at nanointerfaces between water and neat organic solvents. Abstract Text:

Peng Sun, Laforge,Michael V Mirkin,

Nanopipet voltammetry was used for the first study of ion transfer (IT) reactions between aqueous solutions and neat organic solvents. An extremely wide ( approximately 10 V) polarization window obtained with no electrolyte added to the organic phase allows one to probe charge transfer reactions, which are not normally accessible by electrochemical techniques, for example, the transfer of l-alaninamide cation from water to 1,2-dichloroethane (DCE). While anions (e.g., chloride) and relatively hydrophobic cations (e.g., tetraalkylammonium ions) can be transferred from water to less polar neat solvents such as DCE, the transfers of strongly hydrated metal cations occur only in the presence of organic supporting electrolyte.

Ion transfer at nanointerfaces between water and neat organic solvents. Publishing Authors By Initials

P Sun,FO Laforge,MV Mirkin,

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Ion transfer at nanointerfaces between water and neat organic solvents. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 8596-7

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 22

MONTH: Jun

YEAR: 2005

Ion transfer at nanointerfaces between water and neat organic solvents. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Ion transfer at nanointerfaces between water and neat organic solvents.

AFFILIATION: Department of Chemistry and Biochemistry, Queens College-CUNY, Flushing, New York 11367, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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