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Ion-pair formation dynamics of F(2) at 18.385 eV studied by velocity map imaging method.

Ion-pair formation dynamics of F(2) at 18.385 eV studied by velocity map imaging method. Research Abstract Details 

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  • Ion-pair formation dynamics of F(2) at 18.385 eV studied by velocity map imaging method. Abstract Text:

    yusong haoYusong Hao,chang zhouChang Zhou,yuxiang moYuxiang Mo,yusong haoYusong Hao,chang zhouChang Zhou,yuxiang moYuxiang Mo,

    We studied the ion-pair formation dynamics of F2 at 18.385 eV (67.439 nm) using the velocity map imaging method. It was found that there are two dissociation channels corresponding to production of F(+)((1)D(2)) + F(-)((1)S(0)) and F(+)((3)P(j)) + F(-)((1)S(0)). The measured center-of-mass translational energy distribution shows that about 98% of the dissociation occurs via the F(+)((1)D(2)) channel. The measured angular distributions of the photofragments indicate that dissociation for the F(+)((3)P(j)) channel occurs via predissociation of Rydberg states converging to F(2)(+)(A(2)Pi(u)) and dissociation for the F(+)((1)D(2)) channel involves mainly a direct perpendicular transition into the ion-pair state, or X(1)Sigma(g)(+) --> 2(1)Pi(u), which is also supported by the transition dipole moment calculations .

    Ion-pair formation dynamics of F(2) at 18.385 eV studied by velocity map imaging method. Publishing Authors By Initials

    y haoY Hao,c zhouC Zhou,y moY Mo,y haoY Hao,c zhouC Zhou,y moY Mo,

    For similar abstracts research abstracts see: abstracts research

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    Ion-pair formation dynamics of F(2) at 18.385 eV studied by velocity map imaging method. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: The journal of physical chemistry. A

    VOLUME: 111

    Page Numbers: 10887-90

    Journal Abbreviation:

    ISSN: 1089-5639

    DAY: 11

    MONTH: 10

    YEAR: 2007

    Ion-pair formation dynamics of F(2) at 18.385 eV studied by velocity map imaging method. Information

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    LANGUAGE: eng

    NlmUniqueID: 9890903

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    Grant and Affiliation Information for Ion-pair formation dynamics of F(2) at 18.385 eV studied by velocity map imaging method.

    AFFILIATION: Department of Physics, Key Laboratory for Atomic and Molecular Nanosciences, Tsinghua University, Beijing 100084, China.

    Country: United States

    United States Research PublicationUnited States Research Publication

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    MEDLINETA: J Phys Chem A

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