Interrupted Nazarov cyclization on silica gel.

Interrupted Nazarov cyclization on silica gel. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

Interrupted Nazarov cyclization on silica gel. Abstract Text:

Francis Dhoro,Marcus A Tius,

Exposure of a mixture of propargyl vinyl ketone and a nucleophilic primary or secondary amine to activated dry silica gel in the absence of solvent leads to a cascade of reactions that results in the formation of an aminocyclopentenone. The reaction with triethylamine leads to a cross-conjugated cyclopentadienone.

Interrupted Nazarov cyclization on silica gel. Publishing Authors By Initials

F Dhoro,MA Tius,

For similar inorganic chemicals: minerals: silicon dioxide research abstracts see: inorganic chemicals: minerals: silicon dioxide research

PUBMED ID PMID:

MEDLINE DATE:

Interrupted Nazarov cyclization on silica gel. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 12472-3

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 14

MONTH: Sep

YEAR: 2005

Interrupted Nazarov cyclization on silica gel. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Interrupted Nazarov cyclization on silica gel. Keywords Mesh Terms:

KEYWORDS: Silicon Dioxide

MESH TERMS: chemistry

Chemical & Substance for Abstract: Interrupted Nazarov cyclization on silica gel. Information

Substance Name: Silicon Dioxide

Registry Number: 7631-86-9

Grant and Affiliation Information for Interrupted Nazarov cyclization on silica gel.

AFFILIATION: Department of Chemistry, 2545 The Mall, University of Hawaii, Honolulu, Hawaii 96822, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: GM57873

ACRONYM: GM

MEDLINETA: J Am Chem Soc

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

Interrupted Nazarov cyclization on silica gel Related Publications

• An improved chiral auxiliary for the allene ether version of the Nazarov cyclization.
• Design of chiral auxiliaries for the allene ether nazarov cyclization.
• Interrupted Nazarov cyclization on silica gel.
• Interrupting the nazarov cyclization with indoles.
• Oxaza adamantyl cannabinoids. A new class of cannabinoid receptor probes.
• Synthesis of (+)-madindoline A and (+)-madindoline B.
• Total synthesis of (+/-)-terpestacin and (+/-)-11-epi-terpestacin.