Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix.

Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix. Research Abstract Details 

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Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix. Abstract Text:

Angel A ,Noritza Rivera,Karla Soto,Lorena Maldonado,Jorge L ,

The intercalation of fac-tricarbonylchloro-1,10-phenanthrolinerhenium(i) (Re(phen)(CO)(3)Cl) within zirconium phosphate (ZrP) has been achieved using a hydrated ZrP phase that possesses six water molecules per formula unit. This intercalation occurs only at high solution molar ratios (Re : ZrP, 3 : 1) and is characterized by the emergence of a new phase in the X-ray powder diffraction (XRPD) pattern with an interlayer distance of 15.6 A. The XRPD patterns show a decrease in the crystallinity upon intercalation of the inorganic complex. The MLCT absorption bands of Re(phen)(CO)(3)Cl-containing ZrP materials are red shifted in comparison with the complex in acetonitrile whilst the luminescence spectra at different loading levels are blue shifted up to 30 nm in comparison with the complex in acetonitrile. This blue shift is consistent with the rigidochromic effect. The luminescence lifetime of Re(phen)(CO)(3)Cl within ZrP was increased in comparison with its lifetime in acetonitrile solution but is shorter than that of Re(phen)(CO)(3)Cl in frozen glass and polyesther resins. To our knowledge, this is the first example of a water insoluble metal complex intercalated within the layers of ZrP, which opens up new possibilities in the intercalation chemistry of this lamellar material and in the study of host-guest interactions.

Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix. Publishing Authors By Initials

AA ,N Rivera,K Soto,L Maldonado,JL ,

For similar inorganic chemicals: elements: metals, heavy: zirconium research abstracts see: inorganic chemicals: elements: metals, heavy: zirconium research

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Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix. Journal Published:

PUBLICATION TYPE: Research Support, N.I.H., Extr

Journal: Dalton transactions (Cambridge, England : 2003)

VOLUME:

Page Numbers: 1713-8

Journal Abbreviation:

ISSN: 1477-9226

DAY: 9

MONTH: 03

YEAR: 2007

Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix. Information

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LANGUAGE: eng

NlmUniqueID: 101176026

Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix. Keywords Mesh Terms:

KEYWORDS: Zirconium

MESH TERMS: chemistry

Chemical & Substance for Abstract: Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix. Information

Substance Name: Water

Registry Number: 7732-18-5

Grant and Affiliation Information for Intercalation of Re(phen)(CO)3Cl into zirconium phosphate: a water insoluble inorganic complex immobilized in a highly polar rigid matrix.

AFFILIATION: Department of Chemistry, P.O. Box 23346, University of Puerto Rico, Río Piedras, Puerto Rico.

Country: England

AGENCY: United States NIGMS

GRANT: S06GM08102

ACRONYM: GM

MEDLINETA: Dalton Trans

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