Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes.

Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes. Research Abstract Details 

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Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes. Abstract Text:

The reaction of phenyl azide with (PNP)Ni, where PNP = ( (t)Bu 2PCH 2SiMe 2) 2N (-), promptly evolves N 2 and forms a P=N bond in the product (PNP=NPh)Ni (I). A similar reaction with (PNP)FeCl proceeds to form a P=N bond but without N 2 evolution, to furnish (PNP=N-N=NPh)FeCl. An analogous reaction with (PNP)RuCl occurs with a more dramatic redox change at the metal (and N 2 evolution), to give the salt composed of (PNP)Ru(NPh) (+) and (PNP)RuCl 3 (-), together with equimolar (PNP)Ru(NPh). The contrast among these results is used to deduce what conditions favor N 2 loss and oxidative incorporation of the NPh fragment from PhN 3 into a metal complex.

Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes. Publishing Authors By Initials

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Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Inorganic chemistry

VOLUME: 47

Page Numbers: 9002-9

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ISSN: 1520-510X

DAY: 30

MONTH: 08

YEAR: 2008

Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes.

AFFILIATION: Department of Chemistry, Indiana University, Bloomington, Indiana 47405, USA.

Country: United States

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MEDLINETA: Inorg Chem

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