Hydroboration with pyridine borane at room temperature.

Hydroboration with pyridine borane at room temperature. Research Abstract Details 

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Hydroboration with pyridine borane at room temperature. Abstract Text:

Julia M Clay,Edwin Vedejs,

Treatment of pyridine borane (Py.BH3) with iodine, bromine, or strong acids affords activated Py.BH2X complexes that are capable of hydroborating alkenes at room temperature. Evidence is presented for an unusual hydroboration mechanism involving leaving group displacement. In contrast to THF.BH3, hydroboration with Py.BH2I selectively affords the monoadducts. The crude hydroboration products are converted into synthetically useful potassium alkyltrifluoroborate salts upon treatment with methanolic KHF2.

Hydroboration with pyridine borane at room temperature. Publishing Authors By Initials

JM Clay,E Vedejs,

For similar environment and public health: environment: environment, controlled: temperature research abstracts see: environment and public health: environment: environment, controlled: temperature research

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Hydroboration with pyridine borane at room temperature. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 5766-7

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 27

MONTH: Apr

YEAR: 2005

Hydroboration with pyridine borane at room temperature. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Hydroboration with pyridine borane at room temperature. Keywords Mesh Terms:

KEYWORDS: Temperature

MESH TERMS: chemistry

Chemical & Substance for Abstract: Hydroboration with pyridine borane at room temperature. Information

Substance Name: pyridine borane

Registry Number: 110-51-0

Grant and Affiliation Information for Hydroboration with pyridine borane at room temperature.

AFFILIATION: Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: R01 GM067146-02

ACRONYM: GM

MEDLINETA: J Am Chem Soc

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