Halide-induced supramolecular ligand rearrangement.

Halide-induced supramolecular ligand rearrangement. Research Abstract Details 

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Halide-induced supramolecular ligand rearrangement. Abstract Text:

Aaron M Brown,Maxim V Ovchinnikov,Charlotte L Stern,Chad A Mirkin,

A novel reaction involving the halide-induced rearrangement of ligands within supramolecular Rh(I) complexes containing hemilabile ligands is presented. Three analogous bis- and trishemilabile ligands have been synthesized to construct bi- and trimetallic Rh(I) macrocyclic complexes. An intentionally added halide source results in the formal rotation of only one hemilabile ligand along the axis that is perpendicular to the plane defined by the aryl backbone of the hemilabile ligands. X-ray structures, as determined by X-ray crystallography, of key intermediates and products are presented.

Halide-induced supramolecular ligand rearrangement. Publishing Authors By Initials

AM Brown,MV Ovchinnikov,CL Stern,CA Mirkin,

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Halide-induced supramolecular ligand rearrangement. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 14316-7

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 10

MONTH: Nov

YEAR: 2004

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LANGUAGE: eng

NlmUniqueID: 7503056

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Grant and Affiliation Information for Halide-induced supramolecular ligand rearrangement.

AFFILIATION: Department of Chemistry and the Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60201-3113, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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