Formation of giant solvation shells around fulleride anions in liquid ammonia.

Formation of giant solvation shells around fulleride anions in liquid ammonia. Research Abstract Details 

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Formation of giant solvation shells around fulleride anions in liquid ammonia. Abstract Text:

Christopher A Howard,Helen Thompson,Jonathan C Wasse,Neal T Skipper,

Here, we measure the solvation structure of fulleride C605- anions in potassium ammonia solution using neutron diffraction. We find a very strong solvation structure consisting of two shells of ammonia densely packed around the anion. The system's structure is driven by the propensity of ammonia molecules to direct one of their hydrogen bonds to the center of the anion while retaining axial hydrogen bonding within the shells. This permits high concentrations of solvent separated fulleride anions.

Formation of giant solvation shells around fulleride anions in liquid ammonia. Publishing Authors By Initials

CA Howard,H Thompson,JC Wasse,NT Skipper,

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Formation of giant solvation shells around fulleride anions in liquid ammonia. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 13228-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 20

MONTH: Oct

YEAR: 2004

Formation of giant solvation shells around fulleride anions in liquid ammonia. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

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Grant and Affiliation Information for Formation of giant solvation shells around fulleride anions in liquid ammonia.

AFFILIATION: London Centre for Nanotechnology, Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK.

Country: United States

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MEDLINETA: J Am Chem Soc

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