Fluorescence Response of a 4-Trifluoroacetylaminophthalimide to Iodide Ions upon 254 nm Irradiation in MeCN.

Fluorescence Response of a 4-Trifluoroacetylaminophthalimide to Iodide Ions upon 254 nm Irradiation in MeCN. Research Abstract Details 

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Fluorescence Response of a 4-Trifluoroacetylaminophthalimide to Iodide Ions upon 254 nm Irradiation in MeCN. Abstract Text:

The title trifluoroacetylaminophthalimide derivative produced a violet fluorescence (lambda (FL) max 392 nm) in MeCN, and it displayed a green emission (lambda (FL) max 506 nm) after irradiation at 254 nm in the presence of iodide ions. The corresponding amidate ion of the trifluoroacetamide was identified as the green fluorescence emitter. The deprotonation reaction may be caused by proton-abstracting solvated electrons generated by a photochemical charge-transfer-to-solvent process from I (-) to MeCN.

Fluorescence Response of a 4-Trifluoroacetylaminophthalimide to Iodide Ions upon 254 nm Irradiation in MeCN. Publishing Authors By Initials

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Fluorescence Response of a 4-Trifluoroacetylaminophthalimide to Iodide Ions upon 254 nm Irradiation in MeCN. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Organic letters

VOLUME: 10

Page Numbers: 3125-8

Journal Abbreviation: Org. Lett.

ISSN: 1523-7060

DAY: 25

MONTH: 06

YEAR: 2008

Fluorescence Response of a 4-Trifluoroacetylaminophthalimide to Iodide Ions upon 254 nm Irradiation in MeCN. Information

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LANGUAGE: eng

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