Flavin catalyzed oxidations of sulfides and amines with molecular oxygen.

Flavin catalyzed oxidations of sulfides and amines with molecular oxygen. Research Abstract Details 

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Flavin catalyzed oxidations of sulfides and amines with molecular oxygen. Abstract Text:

Yasushi Imada,Hiroki Iida,Satoshi Ono,Shun-Ichi Murahashi,

Novel biomimetic, aerobic oxidation with an organocatalyst was performed. The oxidations of organic substrates such as sulfides, secondary amines, N-hydroxylamines, and tertiary amines with molecular oxygen (1 atm) or even in air in the presence of 5-ethyl-3-methyllumiflavinium perchlorate catalyst and hydrazine monohydrate in 2,2,2-trifluoroethanol occur highly efficiently to give the corresponding oxidized compounds in excellent yields along with water and molecular nitrogen, which are environmentally benign. The TON of the oxidation of sulfides amounts to 19 000.

Flavin catalyzed oxidations of sulfides and amines with molecular oxygen. Publishing Authors By Initials

Y Imada,H Iida,S Ono,S Murahashi,

For similar inorganic chemicals: electrolytes: ions: anions: sulfides research abstracts see: inorganic chemicals: electrolytes: ions: anions: sulfides research

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Flavin catalyzed oxidations of sulfides and amines with molecular oxygen. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Journal of the American Chemical Society

VOLUME: 125

Page Numbers: 2868-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 12

MONTH: Mar

YEAR: 2003

Flavin catalyzed oxidations of sulfides and amines with molecular oxygen. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Flavin catalyzed oxidations of sulfides and amines with molecular oxygen. Keywords Mesh Terms:

KEYWORDS: Sulfides

MESH TERMS: chemistry

Chemical & Substance for Abstract: Flavin catalyzed oxidations of sulfides and amines with molecular oxygen. Information

Substance Name: dimethylaniline monooxygenase (N-oxide f

Registry Number: EC 1.14.13.8

Grant and Affiliation Information for Flavin catalyzed oxidations of sulfides and amines with molecular oxygen.

AFFILIATION: Department of Chemistry, Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka 560-8531, Japan. mura@chem.es.osaka-u.ac.jp

Country: United States

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MEDLINETA: J Am Chem Soc

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