First isocyanoazulene and its homoleptic complexes.

First isocyanoazulene and its homoleptic complexes. Research Abstract Details 

Research Abstract Table of Contents

Jump to the:

First isocyanoazulene and its homoleptic complexes. Abstract Text:

Randall E Robinson,Thomas C Holovics,Stephan F Deplazes,Gerald H Lushington,Douglas R Powell,Mikhail V Barybin,

An efficient synthesis of remarkably stable 6-isocyanoazulene (CN6Az), the first nonbenzenoid organic isocyanide, is described. Its superb pi-accepting potential as a ligand was demonstrated through cyclic voltammetry studies on the binary complexes [Cr(CN6Az)6]0/+. The paramagnetic shift patterns for [Cr(CN6Az)6]+, the only azulenic pi-system studied by paramagnetic NMR, suggest that Cr(dpi) --> CN6Az(ppi*) electron delocalization involves both rings of the azulenyl substituents in [Cr(CN6Az)6]+. This conclusion is supported by density functional theory calculations on the complex [Cr(CN6Az)6][BF4].

First isocyanoazulene and its homoleptic complexes. Publishing Authors By Initials

RE Robinson,TC Holovics,SF Deplazes,GH Lushington,DR Powell,MV Barybin,

For similar biochemical phenomena, metabolism, and nutrition: biochemical phenomena: molecular structure research abstracts see: biochemical phenomena, metabolism, and nutrition: biochemical phenomena: molecular structure research

PUBMED ID PMID:

MEDLINE DATE:

First isocyanoazulene and its homoleptic complexes. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 125

Page Numbers: 4432-3

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 16

MONTH: Apr

YEAR: 2003

First isocyanoazulene and its homoleptic complexes. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

First isocyanoazulene and its homoleptic complexes. Keywords Mesh Terms:

KEYWORDS: Molecular Structure

MESH TERMS: chemistry

Chemical & Substance for Abstract: First isocyanoazulene and its homoleptic complexes. Information

Substance Name: azulene

Registry Number: 275-51-4

Grant and Affiliation Information for First isocyanoazulene and its homoleptic complexes.

AFFILIATION: Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS 66045, USA.

Country: United States

AGENCY:

GRANT:

ACRONYM:

MEDLINETA: J Am Chem Soc

REFSOURCE:

DATABASENAME:

ACCESSION NUMBER:

Number Hits: 0

First isocyanoazulene and its homoleptic complexes Related Publications

• First isocyanoazulene and its homoleptic complexes.
• Multipoint anchoring of the [2.2.2.2]metacyclophane motif to a gold surface via self-assembly: coordination chemistry of a cyclic tetraisocyanide revisited.
• [Effects of tumor necrosis factor on the tonus of cerebral arteries]