Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex.

Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Research Abstract Details 

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Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Abstract Text:

Lei Li,Amy A Narducci Sarjeant,Michael A Vance,Lev N Zakharov,Arnold L Rheingold,Edward I Solomon,Kenneth D Karlin,

A dicopper(I)/phenol-ligand complex in RCN solvents reacts with O2 producing a mu-1,1-hydroperoxo dicopper(II) species. Subsequent thermal transformation results in nitrile hydroxylation and elimination of cyanide, as revealed by the isolation in comparable yields of (i) a cyanide-bridged tetranuclear cluster complex and (ii) benzaldehyde (for R = PhCH2); 18O labeling confirms that the PhC(O)H oxygen atom derives from O2.

Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Publishing Authors By Initials

L Li,AA Narducci Sarjeant,MA Vance,LN Zakharov,AL Rheingold,EI Solomon,KD Karlin,

For similar organic chemicals: nitriles research abstracts see: organic chemicals: nitriles research

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Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Journal Published:

PUBLICATION TYPE: Research Support, N.I.H., Extr

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 15360-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 9

MONTH: Nov

YEAR: 2005

Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Keywords Mesh Terms:

KEYWORDS: Nitriles

MESH TERMS: chemistry

Chemical & Substance for Abstract: Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Information

Substance Name: Hydrogen Peroxide

Registry Number: 7722-84-1

Grant and Affiliation Information for Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex.

AFFILIATION: Department of Chemistry, The Johns Hopkins University, Baltimore, MD 21218, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: GM 28962

ACRONYM: GM

MEDLINETA: J Am Chem Soc

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