Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate.

Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate. Research Abstract Details 

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Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate. Abstract Text:

Ricardo Lira,William R Roush,

syn-beta-Hydroxyallylsilanes of general structure 11 and 28 are prepared in 50-86% yield and 91-95% ee (for aliphatic aldehydes; 50% ee for benzaldehyde) via the BF(3).Et(2)O-promoted gamma-silylallylboration reactions, using reagents 14 and 15.

Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate. Publishing Authors By Initials

R Lira,WR Roush,

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Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate. Journal Published:

PUBLICATION TYPE: Research Support, N.I.H., Extr

Journal: Organic letters

VOLUME: 9

Page Numbers: 4315-8

Journal Abbreviation: Org. Lett.

ISSN: 1523-7060

DAY: 15

MONTH: 09

YEAR: 2007

Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate. Information

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LANGUAGE: eng

NlmUniqueID: 100890393

Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate. Keywords Mesh Terms:

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Grant and Affiliation Information for Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate.

AFFILIATION: Department of Chemistry, Scripps Florida, Jupiter, Florida 33458, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: GM 38436

ACRONYM: GM

MEDLINETA: Org Lett

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