Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions.

Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions. Research Abstract Details 

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Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions. Abstract Text:

Glen Baghdasarian,K A Woerpel,

Nucleophilic substitution reactions of 4-substituted cyclohexanone acetals display different selectivities depending upon the electronic nature of the substituent. Alkyl groups favor equatorial positions in the oxocarbenium ions, but alkoxy groups prefer axial conformers. The reactions of acetals with alkoxy groups constrained to either equatorial or axial positions suggest that the presence of an axial alkoxy group distorts the oxocarbenium ion, changing its inherent preferences for facial attack.

Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions. Publishing Authors By Initials

G Baghdasarian,KA Woerpel,

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Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: The Journal of organic chemistry

VOLUME: 71

Page Numbers: 6851-8

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ISSN: 0022-3263

DAY: 1

MONTH: Sep

YEAR: 2006

Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions.

AFFILIATION: Department of Chemistry, University of California-Irvine, Irvine, CA 92697-2025, USA.

Country: United States

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MEDLINETA: J Org Chem

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