Electrochemical studies of verdazyl radicals.

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Electrochemical studies of verdazyl radicals. Abstract Text:

Joe B Gilroy,Stephen D J McKinnon,Bryan D Koivisto,Robin G Hicks,Joe B Gilroy,Stephen D J McKinnon,Bryan D Koivisto,Robin G Hicks,

The redox properties of verdazyl radicals are presented using cyclic voltammetry techniques. These radicals can be reversibly reduced as well as oxidized. Electron-donating and -withdrawing substituents have significant effects on the oxidation and reduction potentials as well as the cell potential (E(cell) = | E(ox) degrees - E(red) degrees |) for these radicals; a correlation between the electron spin distribution and redox properties is developed.

Electrochemical studies of verdazyl radicals. Publishing Authors By Initials

JB Gilroy,SD McKinnon,BD Koivisto,RG Hicks,JB Gilroy,SD McKinnon,BD Koivisto,RG Hicks,

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Electrochemical studies of verdazyl radicals. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Organic letters

VOLUME: 9

Page Numbers: 4837-40

Journal Abbreviation: Org. Lett.

ISSN: 1523-7060

DAY: 10

MONTH: 10

YEAR: 2007

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LANGUAGE: eng

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AFFILIATION: Department of Chemistry, University of Victoria, Victoria, British Columbia, Canada.

Country: United States

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MEDLINETA: Org Lett

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