Electrochemical generation of glycosyl triflate pools.

Electrochemical generation of glycosyl triflate pools. Research Abstract Details 

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Electrochemical generation of glycosyl triflate pools. Abstract Text:

Toshiki Nokami,Akito Shibuya,Hiroaki Tsuyama,Seiji Suga,Albert A Bowers,David Crich,Jun-ichi Yoshida,

Glycosyl triflates, which serve as important intermediates in glycosylation reactions, were generated and accumulated by the low-temperature electrochemical oxidation of thioglycosides such as thioglucosides, thiogalactosides, and thiomannosides in the presence of tetrabutylammonium triflate (Bu(4)NOTf) as a supporting electrolyte. Thus-obtained solutions of glycosyl triflates (glycosyl triflate pools) were characterized by low-temperature NMR measurements. The thermal stability of glycosyl triflates and their reactions with glycosyl acceptors were also examined.

Electrochemical generation of glycosyl triflate pools. Publishing Authors By Initials

T Nokami,A Shibuya,H Tsuyama,S Suga,AA Bowers,D Crich,J Yoshida,

For similar sulfhydryl compounds research abstracts see: sulfhydryl compounds research

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Electrochemical generation of glycosyl triflate pools. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 129

Page Numbers: 10922-8

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 14

MONTH: 08

YEAR: 2007

Electrochemical generation of glycosyl triflate pools. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Electrochemical generation of glycosyl triflate pools. Keywords Mesh Terms:

KEYWORDS: Sulfhydryl Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Electrochemical generation of glycosyl triflate pools. Information

Substance Name: Methanol

Registry Number: 67-56-1

Grant and Affiliation Information for Electrochemical generation of glycosyl triflate pools.

AFFILIATION: Department of Synthetic Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.

Country: United States

AGENCY: United States NIGMS

GRANT: GM62160

ACRONYM: GM

MEDLINETA: J Am Chem Soc

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