[Effect of different types of counterion on the electronic structure of an antitumor polyoxomolybdate [Mo7O24]6-]

[Effect of different types of counterion on the electronic structure of an antitumor polyoxomolybdate [Mo7O24]6-] Research Abstract Details 

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[Effect of different types of counterion on the electronic structure of an antitumor polyoxomolybdate [Mo7O24]6-] Abstract Text:

Mingli Xiang,Shenxiu Xiao,Zirun Yuan,Yanhui Long,

The electronic structure of a Lindqvist type [Mo7O24]6- anion with 5 different types of counterion (K+, Na+, NH4+, [NH3Pr]+ and [NH3Pri]+) was calculated by using the Discrete Variational Method coupled with Density Functional Theory (DFT-DVM). It could be concluded through variance analysis to the calculated results that the type of counterion does not influence remarkably the electronic structure of [Mo7O24]6- anions. Perhaps it can be used to explain the experiment fact that the polyoxomolybdate structure of the Mo7O24 framework is apparently of critical significance to antitumor action. On these grounds we forecast that two other lindqvist type heptamolybadates(their counterions are Na+ and [NH3Pr]+ respectively) may also exhibit antitumor activities.

[Effect of different types of counterion on the electronic structure of an antitumor polyoxomolybdate [Mo7O24]6-] Publishing Authors By Initials

M Xiang,S Xiao,Z Yuan,Y Long,

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[Effect of different types of counterion on the electronic structure of an antitumor polyoxomolybdate [Mo7O24]6-] Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Sheng wu yi xue gong cheng xue za zhi = Journal of

VOLUME: 19

Page Numbers: 291-6

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ISSN: 1001-5515

DAY: 12

MONTH: Jun

YEAR: 2002

[Effect of different types of counterion on the electronic structure of an antitumor polyoxomolybdate [Mo7O24]6-] Information

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LANGUAGE: chi

NlmUniqueID: 9426398

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Grant and Affiliation Information for [Effect of different types of counterion on the electronic structure of an antitumor polyoxomolybdate [Mo7O24]6-]

AFFILIATION: College of Chemical Engineering, Sichuan University, Chengdu 610065.

Country: China

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MEDLINETA: Sheng Wu Yi Xue Gong Cheng Xue

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