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[Discussion on the concept problem of the specific retention volume in gas chromatography]

[Discussion on the concept problem of the specific retention volume in gas chromatography] Research Abstract Details 

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  • [Discussion on the concept problem of the specific retention volume in gas chromatography] Abstract Text:

    z wuZ Wu,

    The concept problem in the definition of well-known specific retention volume in GC is proposed in this paper. The specific retention volume Vg is usually defined as the net retention volume per gram of liquid phase corrected to 273.15 K in some literatures, and is widely appeared in journals and textbooks as one of the most important absolute retention value in GC, though it is less practical than the relative retention value in the qualitative analysis. Being inspired in the discussion of pressure correction in GC, the author thinks that the temperature correction term in the Vg definition is neither correct nor necessary. The problem was originated from the misunderstanding of the pressure correction of the adjusted retention volume. It is emphasized here that the net retention volume obtained by correction of the adjusted retention volume by compressibility factor j is the retention parameter in term of the column geometrical volume rather than a gas volume. The net retention volume per gram of liquid phase is an absolute retention parameter sufficient to measure the retention power. The author thinks that it is necessary to discuss and clarify the problem to avoid any possible errors being introduced in some cases, such as in the estimation of some thermodynamic parameters.

    [Discussion on the concept problem of the specific retention volume in gas chromatography] Publishing Authors By Initials

    z wuZ Wu,

    For similar abstracts research abstracts see: abstracts research

    PUBMED ID PMID:

    MEDLINE DATE:

    [Discussion on the concept problem of the specific retention volume in gas chromatography] Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Se pu = Chinese journal of chromatography / Zhongg

    VOLUME: 17

    Page Numbers: 315-6

    Journal Abbreviation:

    ISSN: 1000-8713

    DAY: 28

    MONTH: May

    YEAR: 1999

    [Discussion on the concept problem of the specific retention volume in gas chromatography] Information

    Number of References:

    LANGUAGE: chi

    NlmUniqueID: 9424804

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    Grant and Affiliation Information for [Discussion on the concept problem of the specific retention volume in gas chromatography]

    AFFILIATION: Center of Physical and Chemical Analysis, Hebei University, Baoding, 071002.

    Country: China

    China Research PublicationChina Research Publication

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    MEDLINETA: Se Pu

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