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Direct Voltammetric Specific Recognition of Dopamine Using Al(III)-DA Complexes at the Hanging Mercury Drop Electrode.

Direct Voltammetric Specific Recognition of Dopamine Using Al(III)-DA Complexes at the Hanging Mercury Drop Electrode. Research Abstract Details 

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  • Direct Voltammetric Specific Recognition of Dopamine Using Al(III)-DA Complexes at the Hanging Mercury Drop Electrode. Abstract Text:

    fuping zhangFuping Zhang,min zhangMin Zhang,jiongjia chengJiongjia Cheng,li yangLi Yang,ming jiMing Ji,shuping biShuping Bi,fuping zhangFuping Zhang,min zhangMin Zhang,jiongjia chengJiongjia Cheng,li yangLi Yang,ming jiMing Ji,shuping biShuping Bi,fuping zhangFuping Zhang,min zhangMin Zhang,jiongjia chengJiongjia Cheng,li yangLi Yang,ming jiMing Ji,shuping biShuping Bi,

    In this paper, we firstly report the direct voltammetric recognition and determination of dopamine (DA) by using Al(III)-DA complexes at the hanging mercury drop electrode (HMDE). A new sensitive cathodic peak of Al(III)-DA can be detected at -900 mV (vs. SCE) in 0.1 M NH(4)Cl-NH(3).H(2)O-0.1 M KCl buffer solution at pH 8.5. This unique -900 mV cathodic peak arises from the specific interaction between Al(III) and DA on the HMDE, whereas other substances with similar structures, such as L-dopa, epinephrine (EP), norepinephrine (NE), catechols, caffeic acid (CA), trihydric phenols and tiron, do not yield any new peak on the voltammograms in the potential range from -100 to -1200 mV when Al(III) is added. The distinct voltammetric characteristic of the recognition of DA can effectively inhibit the interferences of both ascorbic acid and uric acid in the DA determination by the direct electrochemistry, which is a major difficulty when a solid electrode is used. The proposed method can be anticipated as an effective means for the recognition of DA in the elucidation of the mechanisms of Parkinson's disease (PD) and Alzheimer's disease (AD) in the presence of Al(III).

    Direct Voltammetric Specific Recognition of Dopamine Using Al(III)-DA Complexes at the Hanging Mercury Drop Electrode. Publishing Authors By Initials

    f zhangF Zhang,m zhangM Zhang,j chengJ Cheng,l yangL Yang,m jiM Ji,s biS Bi,f zhangF Zhang,m zhangM Zhang,j chengJ Cheng,l yangL Yang,m jiM Ji,s biS Bi,f zhangF Zhang,m zhangM Zhang,j chengJ Cheng,l yangL Yang,m jiM Ji,s biS Bi,

    For similar abstracts research abstracts see: abstracts research

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    Direct Voltammetric Specific Recognition of Dopamine Using Al(III)-DA Complexes at the Hanging Mercury Drop Electrode. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Analytical sciences : the international journal of

    VOLUME: 23

    Page Numbers: 1325-9

    Journal Abbreviation:

    ISSN: 0910-6340

    DAY: 13

    MONTH: Nov

    YEAR: 2007

    Direct Voltammetric Specific Recognition of Dopamine Using Al(III)-DA Complexes at the Hanging Mercury Drop Electrode. Information

    Number of References:

    LANGUAGE: eng

    NlmUniqueID: 8511078

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    Grant and Affiliation Information for Direct Voltammetric Specific Recognition of Dopamine Using Al(III)-DA Complexes at the Hanging Mercury Drop Electrode.

    AFFILIATION: School of Chemistry & Chemical Engineering, MOE Key Laboratory for Life Science & State Key Laboratory of Coordination Chemistry of China, Nanjing University.

    Country: Japan

    Japan Research PublicationJapan Research Publication

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    MEDLINETA: Anal Sci

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