Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions.

Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions. Research Abstract Details 

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Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions. Abstract Text:

Xue Cui,Hongzhu Ma,Bo Wang,Hongwei Chen,Xue Cui,Hongzhu Ma,Bo Wang,Hongwei Chen,

The direct oxidation of n-heptane to ester using air as the oxidant under mild conditions assisted by sulfated tin oxide (SO(4)(2-)/SnO(2)) and Co modified sulfated tin oxide (SO(4)(2-)/SnO(2)-Co(2)O(3)) prepared by chemical co-precipitation method and characterized by means of SEM, XRD, FT-IR and XPS techniques was studied. From the results it was found that the catalytic activity of SO(4)(2-)/SnO(2)-Co(2)O(3) is higher than that of SO(4)(2-)/SnO(2) in this target reaction, and two asymmetric esters: diisobutyl phthalate and cyclohexylmethyl tridecyl oxalate that have not been reported in the directly oxidation of n-heptane by traditional method have been obtained. The possible mechanism was also discussed.

Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions. Publishing Authors By Initials

X Cui,H Ma,B Wang,H Chen,X Cui,H Ma,B Wang,H Chen,

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Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of hazardous materials

VOLUME: 147

Page Numbers: 800-5

Journal Abbreviation: J. Hazard. Mater.

ISSN: 0304-3894

DAY: 2

MONTH: 02

YEAR: 2007

Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Direct oxidation of n-heptane to ester over modified sulfated SnO2 catalysts under mild conditions.

AFFILIATION: Institute of Energy-Chemistry, College of Chemistry and Materials Science, Shaanxi Normal University, 710062 Xi'an, PR China.

Country: Netherlands

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MEDLINETA: J Hazard Mater

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