Diastereoselective carboxyl migrations of 3-arylbenzofuranones.

Diastereoselective carboxyl migrations of 3-arylbenzofuranones. Research Abstract Details 

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Diastereoselective carboxyl migrations of 3-arylbenzofuranones. Abstract Text:

Gorka Peris,Edwin Vedejs,Gorka Peris,Edwin Vedejs,

Mixed benzofuranyl carbonates derived from chiral chloroformates rearranged in the presence of nucleophilic catalysts to give C-carboxylated benzofurans with variable dr. The use of chiral nucleophilic catalysts gave modest improvement in dr, but better results were obtained by optimizing auxiliary and catalyst. Thus, 8k was obtained with 9:1 dr.

Diastereoselective carboxyl migrations of 3-arylbenzofuranones. Publishing Authors By Initials

G Peris,E Vedejs,G Peris,E Vedejs,

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Diastereoselective carboxyl migrations of 3-arylbenzofuranones. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: The Journal of organic chemistry

VOLUME: 73

Page Numbers: 1158-61

Journal Abbreviation: J. Org. Chem.

ISSN: 0022-3263

DAY: 8

MONTH: 01

YEAR: 2008

Diastereoselective carboxyl migrations of 3-arylbenzofuranones. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Diastereoselective carboxyl migrations of 3-arylbenzofuranones.

AFFILIATION: Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 gorka.peris@yale.edu.

Country: United States

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MEDLINETA: J Org Chem

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