Dearomatization reactions of aryl-substituted silaaziridines.

Dearomatization reactions of aryl-substituted silaaziridines. Research Abstract Details 

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Dearomatization reactions of aryl-substituted silaaziridines. Abstract Text:

Silaaziridines with an aryl group on either the carbon or the nitrogen atom undergo dearomatization reactions upon treatment with benzaldehyde. The reactions form new bonds ortho to the nitrogen substituents with high diastereoselectivity. These dearomatization processes likely are driven by relief of the considerable ring strain of the silaaziridine.

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Dearomatization reactions of aryl-substituted silaaziridines. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: The Journal of organic chemistry

VOLUME: 73

Page Numbers: 8113-5

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ISSN: 1520-6904

DAY: 3

MONTH: 09

YEAR: 2008

Dearomatization reactions of aryl-substituted silaaziridines. Information

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LANGUAGE: eng

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Country: United States

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MEDLINETA: J Org Chem

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