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Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase.

Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase. Research Abstract Details 

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  • Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase. Abstract Text:

    rangan krishnanRangan Krishnan,charles g riordanCharles G Riordan,

    The tripeptide, Ac-CysGlyCys-CONH2, is utilized as a ligand to bind Ni in a fashion identical to that found at the active site of acetyl coenzyme A synthase. The Ni-peptide construct is a suitable metalloligand for the preparation of larger structures formed via bridging Cys side chains. The complexes Ni(CysGlyCys)Ni(dppe) and Ni(CysGlyCys)Ni(depe) serve as close structural representations for the binuclear subcluster, exhibiting electrochemical properties that demonstrate facile access to the reduced mixed valent Ni(II)Ni(I) state, which binds CO.

    Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase. Publishing Authors By Initials

    r krishnanR Krishnan,cg riordanCG Riordan,

    For similar peptides: oligopeptides research abstracts see: peptides: oligopeptides research

    PUBMED ID PMID:

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    Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase. Journal Published:

    PUBLICATION TYPE: Journal Article

    Journal: Journal of the American Chemical Society

    VOLUME: 126

    Page Numbers: 4484-5

    Journal Abbreviation: J. Am. Chem. Soc.

    ISSN: 0002-7863

    DAY: 14

    MONTH: Apr

    YEAR: 2004

    Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase. Information

    Number of References:

    LANGUAGE: eng

    NlmUniqueID: 7503056

    Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase. Keywords Mesh Terms:

    KEYWORDS: Oligopeptides

    MESH TERMS: metabolism

    Chemical & Substance for Abstract: Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase. Information

    Substance Name: Acetate-CoA Ligase

    Registry Number: EC 6.2.1.1

    Grant and Affiliation Information for Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase.

    AFFILIATION: Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA.

    Country: United States

    United States Research PublicationUnited States Research Publication

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    ACRONYM:

    MEDLINETA: J Am Chem Soc

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    Cys-Gly-Cys tripeptide complexes of nickel: binuclear analogues for the catalytic site in acetyl coenzyme a synthase Related Publications

     

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