Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins.

Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins. Research Abstract Details 

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Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins. Abstract Text:

,Ana Caballero,M Mar ,Swiatoslaw Trofimenko,Tomas R ,Pedro J ,

Cu(I) complexes containing trispyrazolylborate ligands efficiently catalyze the atom transfer radical addition (ATRA) of polyhalogenated alkanes to various olefins under mild conditions. The catalytic activity is enhanced when bulky and electron donating Tpx ligands are employed. Kinetic data have allowed the proposal of a mechanistic interpretation that includes a Cu(II) pentacoordinated species that regulates the catalytic cycle.

Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins. Publishing Authors By Initials

JM ,A Caballero,MM ,S Trofimenko,TR ,PJ ,

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Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Inorganic chemistry

VOLUME: 46

Page Numbers: 7725-30

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ISSN: 0020-1669

DAY: 16

MONTH: 05

YEAR: 2007

Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins.

AFFILIATION: Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Campus de El Carmen s/n, Universidad de Huelva, 21007-Huelva, Spain.

Country: United States

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MEDLINETA: Inorg Chem

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