Convergent, Regiospecific Synthesis of Quinolines from o-Aminophenylboronates.

Convergent, Regiospecific Synthesis of Quinolines from o-Aminophenylboronates. Research Abstract Details 

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Convergent, Regiospecific Synthesis of Quinolines from o-Aminophenylboronates. Abstract Text:

A direct convergent two-component synthesis of quinolines from alpha,beta-unsaturated ketones and o-aminophenylboronic acid derivatives is reported. The reaction is regiocomplementary to the traditional Skraup-Doebner-Von Miller synthesis and proceeds under basic rather than strongly acidic conditions. Quinolines substituted in the benzenoid ring can be accessed by using substituted o-aminophenylboronates prepared by direct palladium-catalyzed borylation of the corresponding o-bromoanilines.

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Convergent, Regiospecific Synthesis of Quinolines from o-Aminophenylboronates. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Organic letters

VOLUME: 10

Page Numbers: 4117-20

Journal Abbreviation: Org. Lett.

ISSN: 1523-7052

DAY: 23

MONTH: 08

YEAR: 2008

Convergent, Regiospecific Synthesis of Quinolines from o-Aminophenylboronates. Information

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LANGUAGE: eng

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Country: United States

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MEDLINETA: Org Lett

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