Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates.

Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates. Research Abstract Details 

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Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates. Abstract Text:

K Mani Bushan,Hua Xu,Patrick H Ruane,Raechelle A D'Sa,Christopher M Pavlos,Joseph A Smith,Tevye C Celius,John P Toscano,

The photochemistry of O2-naphthylmethyl- and O2-naphthylallyl-substituted diazeniumdiolates has been investigated. Electron-donating methoxy group substitution is shown to have a significant effect on the observed photochemistry, with the appropriate substitution pattern resulting in efficient diazeniumdiolate photorelease. Observed nitric oxide release rates from these photoprecursors are consistent with those expected for normal thermal dissociation of the diazeniumdiolate in aqueous solutions and show the same pH dependence.

Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates. Publishing Authors By Initials

KM Bushan,H Xu,PH Ruane,RA D'Sa,CM Pavlos,JA Smith,TC Celius,JP Toscano,

For similar natural sciences: chemistry: chemistry, physical: photochemistry: photolysis research abstracts see: natural sciences: chemistry: chemistry, physical: photochemistry: photolysis research

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Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 124

Page Numbers: 12640-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 30

MONTH: Oct

YEAR: 2002

Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates. Keywords Mesh Terms:

KEYWORDS: Photolysis

MESH TERMS: chemistry

Chemical & Substance for Abstract: Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates. Information

Substance Name: Nitric Oxide

Registry Number: 10102-43-9

Grant and Affiliation Information for Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates.

AFFILIATION: Department of Chemistry, Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, USA.

Country: United States

AGENCY: United States NIGMS

GRANT: R01 GM58109

ACRONYM: GM

MEDLINETA: J Am Chem Soc

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