Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts.

Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts. Research Abstract Details 

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Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts. Abstract Text:

Long Zhang,Sanzhong Luo,Xueling Mi,Song Liu,Yupu Qiao,Hui Xu,Jin-Pei Cheng,

A facile combinatorial strategy was developed for the construction of libraries of functionalized chiral ionic liquids (FCILs) including doubly chiral ionic liquids and bis-functional chiral ionic liquids. These FCIL libraries have the potential to be used as asymmetric catalysts or chiral ligands. As an example, novel asymmetric bifunctional catalysts were developed by simultaneously incorporating functional groups onto the cation and anion. The resultant bis-functionalized CILs showed significantly improved stereoselectivity over the mono-functionalized parent CILs.

Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts. Publishing Authors By Initials

L Zhang,S Luo,X Mi,S Liu,Y Qiao,H Xu,JP Cheng,

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Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Organic & biomolecular chemistry

VOLUME: 6

Page Numbers: 567-76

Journal Abbreviation: Org. Biomol. Chem.

ISSN: 1477-0520

DAY: 20

MONTH: 12

YEAR: 2007

Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts.

AFFILIATION: Department of Chemistry and State-key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin, 300071, China.

Country: England

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MEDLINETA: Org Biomol Chem

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