Claisen-type addition of glycine to a pyridoxal iminium ion in water.

Claisen-type addition of glycine to a pyridoxal iminium ion in water. Research Abstract Details 

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Claisen-type addition of glycine to a pyridoxal iminium ion in water. Abstract Text:

Krisztina Toth,Lauren M Gaskell,John P Richard,

The 5'-deoxypyridoxal stabilized glycine carbanion has been generated in water at neutral and mildly basic pH. At pH < 7, this carbanion reacts mainly with the carbonyl carbon of 1 to form a stable Claisen-type adduct. At pH > or = 8, this carbanion reacts with the iminium carbon of the pyridoxal-glycine iminium ion to form the second Claisen-type adduct 3 as the major reaction product.

Claisen-type addition of glycine to a pyridoxal iminium ion in water. Publishing Authors By Initials

K Toth,LM Gaskell,JP Richard,

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Claisen-type addition of glycine to a pyridoxal iminium ion in water. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: The Journal of organic chemistry

VOLUME: 71

Page Numbers: 7094-6

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ISSN: 0022-3263

DAY: 1

MONTH: Sep

YEAR: 2006

Claisen-type addition of glycine to a pyridoxal iminium ion in water. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Claisen-type addition of glycine to a pyridoxal iminium ion in water.

AFFILIATION: Department of Chemistry, University of Buffalo, State University of New York, Buffalo, NY 14260-3000, USA.

Country: United States

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MEDLINETA: J Org Chem

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