Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis.

Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis. Research Abstract Details 

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Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis. Abstract Text:

The Pd-catalysed asymmetric intramolecular alpha-arylation of amide enolates containing heteroatom substituents gives chiral 3-alkoxy or 3-aminooxindoles in high yield and with enantioselectivities up to 97% ee when a new chiral N-heterocyclic carbene ligand is used.

Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis. Publishing Authors By Initials

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Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Chemical communications (Cambridge, England)

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Page Numbers: 4040-2

Journal Abbreviation: Chem. Commun. (Camb.)

ISSN: 1359-7345

DAY: 1

MONTH: 08

YEAR: 2008

Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis. Information

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LANGUAGE: eng

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Grant and Affiliation Information for Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis.

AFFILIATION: Department of Organic Chemistry, University of Geneva, 30 Quai Ernest Ansermet, 1211, Genea 4, Switzerland. Peter.Kundig@.unige.ch.

Country: England

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MEDLINETA: Chem Commun (Camb)

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