Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere.

Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere. Research Abstract Details 

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Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere. Abstract Text:

Masakatsu Matsumoto,Kazutaka Yamada,Nobuko Watanabe,Hisako K Ijuin,Masakatsu Matsumoto,Kazutaka Yamada,Nobuko Watanabe,Hisako K Ijuin,

Bicyclic dioxetanes bearing a 3-(carbazol-9-yl)-5-hydroxyphenyl 2a, 3-hydroxy-5-(indol-1-yl)phenyl 2b, or 3-(benzotriazol-1-yl)-5-hydroxyphenyl group 2c were synthesized. Base-induced decomposition of dioxetane 2a displayed intense light, the maximum wavelength (lambda(max) (CTICL)) of which changed depending on the crown ether complex of potassium t-butoxide used as a base, although the magnitude of lambda(max) (CTICL) change was considerably smaller than the case of dioxetane bearing a 3-(anthracen-9-yl)-5-hydroxyphenyl group 1. Chemiluminescence (CL) from 2b resembled closely that from 2a in response to the crown ether complexes. On the other hand, dioxetane 2c exhibited emission of red light on treatment with tetrabutylammonium fluoride. The colour of light changed significantly and exhibited two peaks in the CL spectrum when treated with complex of bulky dibenzyldiazacrown ether 13.

Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere. Publishing Authors By Initials

M Matsumoto,K Yamada,N Watanabe,HK Ijuin,M Matsumoto,K Yamada,N Watanabe,HK Ijuin,

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Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Luminescence : the journal of biological and chemi

VOLUME: 22

Page Numbers: 420-9

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ISSN: 1522-7235

DAY: 2

MONTH: 10

YEAR: 2007

Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere. Information

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LANGUAGE: eng

NlmUniqueID: 100889025

Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere. Keywords Mesh Terms:

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Chemical & Substance for Abstract: Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere. Information

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Grant and Affiliation Information for Chemiluminescence of bicyclic dioxetanes bearing a hydroxyphenyl moiety substituted with carbazolyl, indolyl or benzotriazolyl group in the coordination sphere.

AFFILIATION: Department of Chemistry, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, Japan. matsumo-chem@kanagawa-u.ac.jp

Country: England

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MEDLINETA: Luminescence

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