Broad-spectrum radical cyclizations boosted by polarity matching. Carbonylative access to alpha-stannylmethylene lactams from azaenynes and CO.

Broad-spectrum radical cyclizations boosted by polarity matching. Carbonylative access to alpha-stannylmethylene lactams from azaenynes and CO. Research Abstract Details 

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Broad-spectrum radical cyclizations boosted by polarity matching. Carbonylative access to alpha-stannylmethylene lactams from azaenynes and CO. Abstract Text:

Ilhyong Ryu,Hironari Miyazato,Hiroki Kuriyama,Kazutoshi Matsu,Mami Tojino,Takahide Fukuyama,Satoshi Minakata,Mitsuo Komatsu,

Free-radical mediated stannylcarbonylation of azaenynes provides a general [n + 1]-type annulation approach leading to alpha-stannylmethylene lactams. The cyclization is unusual in its breadth, covering 4-exo, 5-exo, 6-exo, 7-exo, and 8-exo modes.

Broad-spectrum radical cyclizations boosted by polarity matching. Carbonylative access to alpha-stannylmethylene lactams from azaenynes and CO. Publishing Authors By Initials

I Ryu,H Miyazato,H Kuriyama,K Matsu,M Tojino,T Fukuyama,S Minakata,M Komatsu,

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Broad-spectrum radical cyclizations boosted by polarity matching. Carbonylative access to alpha-stannylmethylene lactams from azaenynes and CO. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 125

Page Numbers: 5632-3

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 14

MONTH: May

YEAR: 2003

Broad-spectrum radical cyclizations boosted by polarity matching. Carbonylative access to alpha-stannylmethylene lactams from azaenynes and CO. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

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Grant and Affiliation Information for Broad-spectrum radical cyclizations boosted by polarity matching. Carbonylative access to alpha-stannylmethylene lactams from azaenynes and CO.

AFFILIATION: Department of Chemistry, Faculty of Arts and Sciences, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan. ryu@ms.cias.osakafu-u.ac.jp

Country: United States

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MEDLINETA: J Am Chem Soc

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