Biphenylene-substituted ruthenocenylphosphine for suzuki-miyaura coupling of aryl chlorides. Abstract Text:
> High activity in the palladium-catalyzed Suzuki-Miyaura reactions of aryl chlorides with arylboronic acids was furnished using biphenylene-substituted di- tert-butylruthenocenylphosphine (R-Phos) as a supporting ligand. Substrate combinations even for the construction of highly hindered tetra- ortho-substituted biaryls can be achieved in good to excellent yields with low catalyst loadings in short reaction times.
Biphenylene-substituted ruthenocenylphosphine for suzuki-miyaura coupling of aryl chlorides. Publishing Authors By Initials
