Bifunctional organocatalyst for methanolytic desymmetrization of cyclic anhydrides: increasing enantioselectivity by catalyst dilution.

Bifunctional organocatalyst for methanolytic desymmetrization of cyclic anhydrides: increasing enantioselectivity by catalyst dilution. Research Abstract Details 

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Bifunctional organocatalyst for methanolytic desymmetrization of cyclic anhydrides: increasing enantioselectivity by catalyst dilution. Abstract Text:

Ho Sik Rho,Sang Ho Oh,Ji Woong Lee,Jin Yong Lee,Jik Chin,Choong Eui Song,

Highly enantioselective methanolysis of meso-cyclic anhydride was achieved with bifunctional organocatalyst containing a quinine-thiourea moiety; unusual concentration, temperature and solvent effects on the enantioselectivity can be explained in terms of a mechanism involving monomer-dimer equilibration of the catalyst.

Bifunctional organocatalyst for methanolytic desymmetrization of cyclic anhydrides: increasing enantioselectivity by catalyst dilution. Publishing Authors By Initials

HS Rho,SH Oh,JW Lee,JY Lee,J Chin,CE Song,

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Bifunctional organocatalyst for methanolytic desymmetrization of cyclic anhydrides: increasing enantioselectivity by catalyst dilution. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Chemical communications (Cambridge, England)

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Page Numbers: 1208-10

Journal Abbreviation: Chem. Commun. (Camb.)

ISSN: 1359-7345

DAY: 6

MONTH: 02

YEAR: 2008

Bifunctional organocatalyst for methanolytic desymmetrization of cyclic anhydrides: increasing enantioselectivity by catalyst dilution. Information

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LANGUAGE: eng

NlmUniqueID: 9610838

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AFFILIATION: Department of Chemistry, Sungkyunkwan University, 300 Cheoncheon, Jangan, Suwon, Gyeonggi, 440-746 Korea. s1673@skku.edu.

Country: England

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MEDLINETA: Chem Commun (Camb)

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