Beyond a T-shape.

Beyond a T-shape. Research Abstract Details 

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Beyond a T-shape. Abstract Text:

Pankaj Sinha,Angela K Wilson,Mohammad A Omary,

Varying the steric bulk of either the phosphine or the halide in Au(PR3)2X complexes allows intuitive tuning of the phosphorescence energy to multiple visible colors, including the coveted blue for LED applications. The excited-state structure involves distortion of the trigonal coordination sphere beyond a T-shape. The [Au(TPA)2]Cl complex exhibits orange phosphorescence due to exciplex formation with the counterion to form the same type of excited state, representing the first example of a luminescent two-coordinate Au(I) complex in absence of both Au...Au interactions and aromatic moieties.

Beyond a T-shape. Publishing Authors By Initials

P Sinha,AK Wilson,MA Omary,

For similar natural sciences: physics: nuclear physics: quantum theory research abstracts see: natural sciences: physics: nuclear physics: quantum theory research

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Beyond a T-shape. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 12488-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 14

MONTH: Sep

YEAR: 2005

Beyond a T-shape. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Beyond a T-shape. Keywords Mesh Terms:

KEYWORDS: Quantum Theory

MESH TERMS: radiation effects

Chemical & Substance for Abstract: Beyond a T-shape. Information

Substance Name: Gold

Registry Number: 7440-57-5

Grant and Affiliation Information for Beyond a T-shape.

AFFILIATION: Department of Chemistry, University of North Texas, Denton, Texas 76203-5070, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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