Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations.

Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Research Abstract Details 

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Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Abstract Text:

Chivukula V Sastri,Mi Joo Park,Takehiro Ohta,Timothy A Jackson,Audria Stubna,Mi Sook Seo,Jimin Lee,Jinheung Kim,Teizo Kitagawa,Eckard ,Lawrence Que,Wonwoo Nam,

Axial ligand substitution of a mononuclear nonheme oxoiron(IV) complex, [FeIV(O)(TMC)(NCCH3)]2+ (1) (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), leads to the formation of new FeIV=O species with relatively intense electronic absorption features in the near-UV region. The presence of these near-UV features allowed us to make the first observation of Fe=O vibrations of S = 1 mononuclear nonheme oxoiron(IV) complexes by resonance Raman spectroscopy. We have also demonstrated that the reactivity of nonheme oxoiron(IV) intermediates is markedly influenced by the axial ligands.

Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Publishing Authors By Initials

CV Sastri,MJ Park,T Ohta,TA Jackson,A Stubna,MS Seo,J Lee,J Kim,T Kitagawa,E ,L Que,W Nam,

For similar biomechanics: vibration research abstracts see: biomechanics: vibration research

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Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 12494-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 14

MONTH: Sep

YEAR: 2005

Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Keywords Mesh Terms:

KEYWORDS: Vibration

MESH TERMS: methods

Chemical & Substance for Abstract: Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Information

Substance Name: Oxygen

Registry Number: 7782-44-7

Grant and Affiliation Information for Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations.

AFFILIATION: Department of Chemistry and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea.

Country: United States

AGENCY: United States NIGMS

GRANT: GM-33162

ACRONYM: GM

MEDLINETA: J Am Chem Soc

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