Asymmetric total synthesis of (+)-phoslactomycin B. Abstract Text:
(+)-Phoslactomycin B was synthesized by a highly enantio- and stereoselective approach involving asymmetric pentenylation, Suzuki-Miyaura coupling, ring-closing metathesis, asymmetric dihydroxylation, and Stille coupling. The synthetic method developed enables us to synthesize three other isomers concerning the C11-OH and Delta (12)-double bond.
Asymmetric total synthesis of (+)-phoslactomycin B. Publishing Authors By Initials