Asymmetric synthesis of syn- and anti-1,3-amino alcohols.

Asymmetric synthesis of syn- and anti-1,3-amino alcohols. Research Abstract Details 

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Asymmetric synthesis of syn- and anti-1,3-amino alcohols. Abstract Text:

Takuya Kochi,Tony P Tang,Jonathan A Ellman,

The first application of metalloenamines derived from N-sulfinyl imines is reported for the highly diastereoselective addition to aldehydes. Reduction of the beta-hydroxy-N-sulfinyl imine products with catecholborane and LiBHEt3 provides syn- and anti-1,3-amino alcohol derivatives, respectively, with very high diastereomeric ratios.

Asymmetric synthesis of syn- and anti-1,3-amino alcohols. Publishing Authors By Initials

T Kochi,TP Tang,JA Ellman,

For similar natural sciences: chemistry: chemistry, organic: isomerism: stereoisomerism research abstracts see: natural sciences: chemistry: chemistry, organic: isomerism: stereoisomerism research

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Asymmetric synthesis of syn- and anti-1,3-amino alcohols. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 124

Page Numbers: 6518-9

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 12

MONTH: Jun

YEAR: 2002

Asymmetric synthesis of syn- and anti-1,3-amino alcohols. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Asymmetric synthesis of syn- and anti-1,3-amino alcohols. Keywords Mesh Terms:

KEYWORDS: Stereoisomerism

MESH TERMS: chemical synthesis

Chemical & Substance for Abstract: Asymmetric synthesis of syn- and anti-1,3-amino alcohols. Information

Substance Name: Amino Alcohols

Registry Number: 0

Grant and Affiliation Information for Asymmetric synthesis of syn- and anti-1,3-amino alcohols.

AFFILIATION: Center for New Directions in Organic Synthesis, Department of Chemistry, University of California, Berkeley, California 94720, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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