Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex.

Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex. Research Abstract Details 

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Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex. Abstract Text:

Ryo Takita,Kenichiro Yakura,Takashi Ohshima,Masakatsu Shibasaki,

Asymmetric alkynylation of both aromatic and aliphatic aldehydes using catalytic amounts of In(III)/BINOL is described. Dual activation of both substrates due to the "bifunctional character" of the indium(III) catalyst enables a broad range of substrate generality with high enantioselectivity (83 to >99% ee).

Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex. Publishing Authors By Initials

R Takita,K Yakura,T Ohshima,M Shibasaki,

For similar organic chemicals: organometallic compounds research abstracts see: organic chemicals: organometallic compounds research

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Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 13760-1

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 12

MONTH: Oct

YEAR: 2005

Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex. Information

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LANGUAGE: eng

NlmUniqueID: 7503056

Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex. Keywords Mesh Terms:

KEYWORDS: Organometallic Compounds

MESH TERMS: chemistry

Chemical & Substance for Abstract: Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex. Information

Substance Name: Indium

Registry Number: 7440-74-6

Grant and Affiliation Information for Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex.

AFFILIATION: Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Country: United States

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MEDLINETA: J Am Chem Soc

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