A convenient, multigram-scale synthesis of arylene ethynylene macrocycles near room temperature is described. Driven by the precipitation of a diarylacetylene byproduct, alkyne metathesis produces the desired macrocycles in one step from monomers in high yields.
Arylene ethynylene macrocycles prepared by precipitation-driven alkyne metathesis. Publishing Authors By Initials
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AFFILIATION: Roger Adams Laboratory, Departments of Chemistry and Materials Science & Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA.
Country: United States
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MEDLINETA: J Am Chem Soc
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