Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene.

Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene. Research Abstract Details 

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Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene. Abstract Text:

Amos B Smith,Dae-Shik Kim,Ming Xian,

Extension of anion relay chemistry (ARC) beyond the area of dithianes has been achieved by the design of two effective ARC linchpins capable of three- and four-component couplings. To showcase the ARC tactic in natural product synthesis, a cytotoxic gorgonian linear sesquiterpene was constructed, and the absolute configuration assigned via the Kakisawa/Mosher method. The synthesis proceeded in five steps with an overall yield of 22%.

Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene. Publishing Authors By Initials

AB Smith,DS Kim,M Xian,

For similar natural sciences: chemistry: chemistry, organic: isomerism: stereoisomerism research abstracts see: natural sciences: chemistry: chemistry, organic: isomerism: stereoisomerism research

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Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene. Journal Published:

PUBLICATION TYPE: Research Support, Non-U.S. Gov

Journal: Organic letters

VOLUME: 9

Page Numbers: 3307-9

Journal Abbreviation: Org. Lett.

ISSN: 1523-7060

DAY: 18

MONTH: 07

YEAR: 2007

Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene. Information

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LANGUAGE: eng

NlmUniqueID: 100890393

Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene. Keywords Mesh Terms:

KEYWORDS: Stereoisomerism

MESH TERMS: chemical synthesis

Chemical & Substance for Abstract: Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene. Information

Substance Name: Sesquiterpenes

Registry Number: 0

Grant and Affiliation Information for Anion relay chemistry extended. Synthesis of a gorgonian sesquiterpene.

AFFILIATION: Department of Chemistry, Monell Chemical Senses Center and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA. smithab@sas.upenn.edu

Country: United States

AGENCY: United States NIGMS

GRANT: GM-29028

ACRONYM: GM

MEDLINETA: Org Lett

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