An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions.

An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions. Research Abstract Details 

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An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions. Abstract Text:

Ken Motokura,Noriaki Fujita,Kohsuke Mori,Tomoo Mizugaki,Kohki Ebitani,Kiyotomi Kaneda,

A Ti4+-exchanged montmorillonite (Ti4+-mont) and a hydrotalcite (HT) are strong solid Brønsted acid and base, and these two clay catalysts could be used in a single reactor without neutralization of active sites. Because the Ti4+-mont have active acid site in the narrow interlayers, the base sites of large HT particles show no interaction with the acid sites. A variety of acid and base reactions, such as esterification, acetalization, deacetalization, aldol reaction, Michael reaction, and epoxidation, proceeded using both the Ti4+-mont and the HT in a single reactor.

An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions. Publishing Authors By Initials

K Motokura,N Fujita,K Mori,T Mizugaki,K Ebitani,K Kaneda,

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An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions. Journal Published:

PUBLICATION TYPE: Journal Article

Journal: Journal of the American Chemical Society

VOLUME: 127

Page Numbers: 9674-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 13

MONTH: Jul

YEAR: 2005

An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions. Information

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LANGUAGE: eng

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Grant and Affiliation Information for An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions.

AFFILIATION: Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan.

Country: United States

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MEDLINETA: J Am Chem Soc

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