Alternating copolymerization of limonene oxide and carbon dioxide.

Alternating copolymerization of limonene oxide and carbon dioxide. Research Abstract Details 

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Alternating copolymerization of limonene oxide and carbon dioxide. Abstract Text:

Christopher M Byrne,Scott D Allen,Emil B Lobkovsky,Geoffrey W Coates,

The alternating copolymerization of (R)- or (S)-limonene oxide and CO2 using beta-diiminate zinc acetate catalysts is reported. At 100 psi CO2 and 25 degrees C, the catalyst exhibits a high selectivity for the trans isomer and produces regioregular polycarbonate. The copolymer contains >99% carbonate linkages, a narrow molecular weight distribution, and an Mn value consistent with the [epoxide]/[Zn] ratio.

Alternating copolymerization of limonene oxide and carbon dioxide. Publishing Authors By Initials

CM Byrne,SD Allen,EB Lobkovsky,GW Coates,

For similar macromolecular substances: polymers research abstracts see: macromolecular substances: polymers research

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Alternating copolymerization of limonene oxide and carbon dioxide. Journal Published:

PUBLICATION TYPE: Research Support, U.S. Gov't,

Journal: Journal of the American Chemical Society

VOLUME: 126

Page Numbers: 11404-5

Journal Abbreviation: J. Am. Chem. Soc.

ISSN: 0002-7863

DAY: 22

MONTH: Sep

YEAR: 2004

Alternating copolymerization of limonene oxide and carbon dioxide. Information

Number of References:

LANGUAGE: eng

NlmUniqueID: 7503056

Alternating copolymerization of limonene oxide and carbon dioxide. Keywords Mesh Terms:

KEYWORDS: Polymers

MESH TERMS: chemical synthesis

Chemical & Substance for Abstract: Alternating copolymerization of limonene oxide and carbon dioxide. Information

Substance Name: Carbon Dioxide

Registry Number: 124-38-9

Grant and Affiliation Information for Alternating copolymerization of limonene oxide and carbon dioxide.

AFFILIATION: Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853, USA.

Country: United States

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MEDLINETA: J Am Chem Soc

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